LTA TIPIDAGI SEOLITNING ANGREN KAOLINI ASOSIDA SINTEZI VA SPEKTROSKOPIK (FTIR) TAHLILI
PDF

Keywords

Angren kaolini
AKF-78
metakaolin
NaA seoliti
LTA strukturasi
gidrotermal sintez
FTIR spektroskopiyasi
D4R
alumosilikat karkas.

How to Cite

LTA TIPIDAGI SEOLITNING ANGREN KAOLINI ASOSIDA SINTEZI VA SPEKTROSKOPIK (FTIR) TAHLILI. (2026). Qo‘qon DPI. Ilmiy Xabarlar Jurnali, 8(9), 223-229. https://doi.org/10.70728/a.series.tab.v08.i09.030

Abstract

Mazkur maqolada Angren kaolining AKF-78 markasi asosida LTA tipidagi NaA seolitini sintez qilish va uning strukturaviy xususiyatlarini FTIR spektroskopiyasi yordamida tadqiq etish natijalari keltirilgan. Kaolinit 650 °C haroratda 5 soat davomida termik ishlov berilib, reaktiv metakaolinga aylantirildi. Metakaolin 2,5 M NaOH eritmasi bilan ishqoriy muhitda qayta ishlanib, hosil qilingan gel 90 °C haroratda 30 soat davomida gidrotermal kristallantirildi. Olingan mahsulot yuvilib, quritilgandan so‘ng FTIR usulida tahlil qilindi. Spektrda 3446 va 1653 cm-1 sohalaridagi signallar adsorbsiyalangan suv molekulalarining tebranishlariga, 1001 cm-1 dagi kuchli yutilish Si–O– Si va Si–O–Al bog‘larining asimmetrik valent tebranishlariga, 552 cm-1 dagi signal esa LTA strukturasiga xos D4R birliklariga tegishli ekanligi aniqlandi. Olingan FTIR natijalari Angren kaolini asosida LTA tipidagi NaA seolitining muvaffaqiyatli sintez qilinganligini tasdiqladi.
PDF

References

1. Hartati, D. Prasetyoko, M. Santoso, I. Qoniah, W.L. Leaw, P.B.D. Firda, H. Nur. A review on synthesis of kaolin-based zeolite and the effect of impurities, Journal of the Chinese Chemical Society, 2020, 67: 911–936.

2. Y. He, S. Tang, S. Yin, S. Li. Research progress on green synthesis of various high-purity zeolites from natural material-kaolin, Journal of Cleaner Production, 2021, 306: 127248.

3. D. Novembre, D. Gimeno, A. Del Vecchio. Synthesis and characterization of Na-P1 (GIS) zeolite using a kaolinitic rock, Scientific Reports, 2021, 11: 4872.

4. N. Sazali, Z. Harun, A. Tijjani, N.H. Kamarudin, N.R. Jamalludin, S.K. Hubadillah, S.S. Alias. The Route of Hydrothermal Synthesis Zeolite-A from the Low-Grade Perak kaolin, Malaysia, Silicon, 2022, 14: 7257–7273.

5. D.C. Son, V.T.K. Anh, N.T. Thom, H.L.T. Nguyen, L.V. Hai, C.T. Thien, N.T. Hoang, T.D. Lam, P.T. Nam, N.T.T. Trang. Preparation and modification of zeolite A from kaolin for catalytic methanation of carbon dioxide, Vietnam Journal of Chemistry, 2023, 61: 170–177.

6. I. Ekpe, H. Mgbemere, G. Lawal, H. Ovri, A.L. Chaudhary. Synthesis of Linde Type A zeolite from Darazo kaolin found in Bauchi State, Nigeria, Asia-Pacific Journal of Science and Technology, 2023, 28: APST-28-04-09.

7. W. Wang, W. Jia, Y. Deng, Q. Sun, et al. Synthesis of 2D type A molecular sieves by alkaline removal of natural kaolin, Functional Materials Letters, 2023.

8. S. Khemaissia, D. Nibou, A. Bentourkia, S. Amokrane, H.A. Hammoudi. Synthesis of zeolite type A from metakaolin obtained by thermal treatment of kaolin: Textural and BB41 dye adsorption experimental design studies, Separation Science and Technology, 2025, 60: 197–219.

9. I.M. Zdretsov, A.M. Gerasimov. Green and low-cost synthesis of zeolites from kaolin: a promising technology or a delusion?, Reaction Chemistry & Engineering, 2024, 9: 1994–2027.

10. G. Akar Şen. Synthesis of zeolite LTA from kaolin and its model CBC and WAC performance: Optimized by central composite design, Journal of the Serbian Chemical Society, 2025, 90: 1223–1239.

11. C.G. Fotsop, A. Lieb, F. Scheffler. Investigating the impact of heating rates on hydrothermal conversion of heat-treated kaolin into Linde-type LTA zeolite for water vapor sorption, Materials Advances, 2025, 6: 8078–8091.

12. C.G. Fotsop, A. Lieb, F. Scheffler. Cameroonian natural clay derived Linde type LTA zeolite: demystifying and understanding the impact of the synthesis process on adsorption efficiency, Materials Advances, 2025, 6: 9678–9695.

13. G. Akar Şen. Synthesis of zeolite LTA from kaolin and its model CBC and WAC performance: Optimized by central composite design, Journal of the Serbian Chemical Society, 2025, 90: 1223–1239.

14. M. Kohi Habibi, S.M. Rafiaei. Hydrothermal/Alkali Fusion Synthesis of Zeolite NaA and NaX from Pyrophyllite Mineral Clay, Transactions of the Indian Institute of Metals, 2024, 77: 1631–1638

15. Z. Chang, Y. Yan, L. Bai, N. Guo, Z. Xing, C. Lu. Synthesis and Characterization of NaA Zeolite from Coal Gangue and Its Efficacy in Cd and Pb Remediation in Water and Soil, ACS Omega, 2024, 9: 51237–51252