MAHALLIY XOMASHYOLAR ASOSIDA YUQORI SAMARALI DEEMULGATORLAR SINTEZ QILISH VA SUV-NEFT EMULSIYALARIDA QO‘LLASH
PDF

Keywords

deemulgator
suv-neft emulsiyasi
soapstok
yog‘ kislotalari
dietanolamin
oksietillash
gidrofil-lipofil balans
IQ-spektroskopiya
kogulyatsiya
neftni suvsizlantirish

How to Cite

MAHALLIY XOMASHYOLAR ASOSIDA YUQORI SAMARALI DEEMULGATORLAR SINTEZ QILISH VA SUV-NEFT EMULSIYALARIDA QO‘LLASH. (2026). Qo‘qon DPI. Ilmiy Xabarlar Jurnali, 8(8), 400-410. https://doi.org/10.70728/a.series.tab.v08.i08.049

Abstract

Maqolada mahalliy xomashyo - paxta moyi rafinatsiyasi (soapstok) dan ajratilgan yog‘ kislotalari asosida noionogen deemulgatorlar sintez qilish natijalari keltirilgan. Yog‘ kislotalarining o‘rtacha molekulyar massasi 274,9 g/mol, kislota soni 204,1 mg KOH ni tashkil etdi. Dietanolamin bilan amidlash orqali molekulyar massasi 362,0 g/mol bo‘lgan alkanolamid 93,4 % unum bilan olindi, kislota sonining 204,1 dan 4,2 mg KOH/g gacha kamayishi konversiya darajasi 97,9 % ekanini ko‘rsatdi. Alkanolamidni 10, 15 va 20 mol etilenoksid bilan oksietillash natijasida molekulyar massalari mos ravishda 802,5, 1022,7 va 1243,0 g/mol, gidrofil-lipofil balansi 10,98, 12,92 va 14,18 bo‘lgan DE-1, DE-2 va DE-3 namunalari sintez qilindi. HLB qiymati 12,9 bo‘lgan DE-2 namunasi optimal ekani aniqlanib, u 50 g/t sarfda va 80 °C haroratda 97,0 % suvsizlanish darajasini taminlagan, qoldiq suv miqdorini 0,18 mass. % gacha, qoldiq tuz miqdorini 42 mg/l gacha kamaytirishga erishilgan.
PDF

References

1. O‘zbekiston Respublikasi Prezidentining 2023-yil 11-sentabrdagi PF-158-son «Ozbekiston - 2030» strategiyasi togrisida»gi Farmoni // Qonun hujjatlari malumotlari milliy bazasi, 12.09.2023, 06/23/158/0722-son.

2. Хрисониди В. А., Струева В. А. Современные методы разрушения водонефтяных эмульсий //The scientific heritage. – 2020. – №. 50-3. – С. 38-41.

3. Чулкова А. О. и др. Эффективность деэмульгаторов в процессе разрушения нефтекислотных эмульсий //Нефтепромысловое дело. – 2016. – Т. 7. – С. 26-29.

4. Корхова И. С., Бузаев В. В., Наумов Ю. Н. Индукционный способ разрушения водонефтяных эмульсий //Интеллектуальный потенциал XXI века: ступени познания. – 2010. – №. 4-2. – С. 35-38.

5. Schramm L.L. Emulsions, Foams, and Suspensions: Fundamentals and Applications. - Weinheim: Wiley-VCH, 2005. - 448 p.

6. Sjöblom J. (ed.) Emulsions and Emulsion Stability. 2nd ed. - Boca Raton: CRC Press, 2006. - 680 p.

7. Kokal S.L. Crude Oil Emulsions: A State-of-the-Art Review // SPE Production & Facilities. - 2005. — Vol. 20, No. 1. - P. 5–13.

8. Goldszal A., Bourrel M. Demulsification of Crude Oil Emulsions: Correlation to Microemulsion Phase Behavior // Industrial & Engineering Chemistry Research. - 2000. - Vol. 39, No. 8. - P. 2746–2751.

9. Griffin W.C. Classification of Surface-Active Agents by HLB // Journal of the Society of Cosmetic Chemists. - 1949. - Vol. 1. - P. 311–326.

10. Rosen M.J., Kunjappu J.T. Surfactants and Interfacial Phenomena. 4th ed. - Hoboken: John Wiley & Sons, 2012. - 616 p.

11. Abdulredha M.M., Aslina H.S., Luqman C.A. Overview on Petroleum Emulsions, Formation, Influence and Demulsification Treatment Techniques // Arabian Journal of Chemistry. - 2020. - Vol. 13, No. 1. - P. 3403–3428.

12. Zolfaghari R., Fakhrul-Razi A., Abdullah L.C. et al. Demulsification Techniques of Water-in-Oil and Oil-in-Water Emulsions in Petroleum Industry // Separation and Purification Technology. - 2016. - Vol. 170. - P. 377-407.

13. Socrates G. Infrared and Raman Characteristic Group Frequencies: Tables and Charts. 3rd ed. - Chichester: John Wiley & Sons, 2004. - 366 p.

14. ГОСТ 2477-2014. Нефть и нефтепродукты. Метод определения содержания воды. - М.: Стандартинформ, 2015. - 12 с.

15. D.S.Boboyev, M.U.Karimov. F.S. Ismoilov “Neft tarkibidagi suvni deemulgatorlar yordamida ajratish usullari” “Development of sciense” 2025/7 Issue

7. Volume 4. https://devos.uz/article.php?id=1454

16. D.S.Boboyev, M.U.Karimov. F.S. Ismoilov “Neft emulsiyalarini deemulgatorlar yordamida ajratish usullari” “Development of sciense” 2025/11 Issue

11. Volume 3. https://devos.uz/article.php?id=2488

17. A.Ochilov. B.Adizov. “Analsys of demulsifier produktion from sulfurized cottonseed oil and breakdown of water-oil emulsions” “The Austrian journal of technikal and natural sciences” N 5-6, section 3.

18. ГОСТ 21534-76. Нефть. Методы определения содержания хлористых солей. - М.: Издательство стандартов, 1998. -14 с.

19. ГОСТ 5476-80. Масла растительные. Методы определения кислотного числа. - М.: Стандартинформ, 2011. - 6 с.

20. O‘z DSt 3239:2017. Neft. Umumiy texnikaviy shartlar. - T.: O‘zstandart, 2017. - 18 b.

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Copyright (c) 2026 Dilshod Sayfullo o'g'li Boboyev, Ma'sud Ubaydullo o'g'li Karimov, Feruz Sabirovich Ismailov (Author)